Download e-book for iPad: Handbook of nonlinear optical crystals by Valentin G. Dmitriev, Gagik G. Gurzadyan, David N.

By Valentin G. Dmitriev, Gagik G. Gurzadyan, David N. Nikogosyan

ISBN-10: 3540653945

ISBN-13: 9783540653943

Because the invention of the 1st laser 30 years in the past, the frequency conversion of laser radiation in nonlinear optical crystals has turn into a big procedure conventional in quantum electronics and laser physics for fixing numerous clinical and engineering difficulties. the elemental physics of three-wave mild interactions in nonlinear optical crystals is now good understood. This has enabled the creation of varied harmonic turbines, sum-and distinction­ frequency turbines, and optical parametric oscillators in keeping with nonlinear optical crystals which are now commercially on hand. while, scientists proceed an energetic look for novel, hugely effective nonlinear optical fabrics. accordingly, in our opinion, there's a nice desire for a instruction manual of nonlinear optical crystals, meant for experts and practitioners with an engineering history. This booklet encompasses a whole description of the houses and purposes of all nonliner optical crystals of functional significance mentioned within the literature as much as the start of 1990. additionally, it includes an important equations for calculating the most parameters (such as phase-matching course, potent nonlinearity, and conversion potency) of nonlinear frequency converters. Dolgoprudnyi, Yerevan, Troitzk v. G. Dmitriev USSR G. G. Gurzadyan October 1990 D. N. Nikogosyan Contents 1 advent. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Optics of Nonlinear Crystals. . . . . . . . . . . . . . . . . . . . . . . . three . . . . . .

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Nevertheless, complex 63 was photochemically inert. 10). Each molecule of 61 forms very strong hydrogen bonds with three different 7a molecules. On the one side, the pyridone oxygen atom forms two strong hydrogen bonds with the hydroxyl groups of two different 7a molecules. 9. X-ray structure of 59, a 1:2 complex of 60 and 54. FUMIO TODA 25 O O OH N H N 61 62 O H N NH HN N H O O 64 65 a: syn-form b: anti-form of 7a. Moreover there are many CϪH…π interactions (at distance around 3 Å) between the molecule of 61 and the aryl groups of 7a.

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These data clearly show that molecules of 60 functioned twice as a host. That is, the mixing of 60 and 54 produces the complex 59 and its photoirradiation gives 56 and 60. By further mixing, excess 54 becomes included with the released host 60, which upon continuous irradiation forms the dimer 56. Isolation of 4-pyridone (61) from an equilibrium mixture with 4-hydroxypyridine (62) was accomplished by inclusion complexation with 7a to give a 1:1 complex 63 of 7a and 61. Since so far photodimerization of 61 has never succeeded, complex 63 is an interesting target compound for photoirradiation experiments.

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Handbook of nonlinear optical crystals by Valentin G. Dmitriev, Gagik G. Gurzadyan, David N. Nikogosyan

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