Crystals and crystallinity in polymers : diffraction by Claudio De Rosa PDF

By Claudio De Rosa

ISBN-10: 0470175761

ISBN-13: 9780470175767

ISBN-10: 1118690443

ISBN-13: 9781118690444

ISBN-10: 1118690591

ISBN-13: 9781118690598

ISBN-10: 1118690796

ISBN-13: 9781118690796

ISBN-10: 1299848710

ISBN-13: 9781299848719

"Polymeric crystals are extra advanced in nature than different fabrics' crystal buildings because of major structural disease current. in reality, they really exist in a semicrystalline country the place the crystals are embedded in an amorphous section to create a hugely interconnected community. proposing an in-depth and present review of polymer crystals, Crystals and Crystallinity in Polymers offers researchers,

"This publication offers a accomplished rationalization and review of the advanced subject of polymer crystallography in a manner that permits readers to judge polymer crystallization facts and ensure which how to make the most of for specific cases"-- Read more...

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Additional info for Crystals and crystallinity in polymers : diffraction analysis of ordered and disordered crystals

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The screw operator cannot combine with the inversion center i, mirror planes m and d, and the glide plane c, which would change the helix sense, while the twofold axis perpendicular to the chain axis is the only symmetry operator compatible with the screw repetition, except the special cases M = 1, N = 1 (s = t), and M = 2, N = 1. 3, have been defined. 2 sufficient to specify the full symmetry of the chain. The conformation of polymers is completely defined in terms of the chain symmetry (3,4,19,21d,e,g,42).

5, are configurationally identical and differ only in the chain orientation. Syndiotactic polymers, defined as regular poly­ mers whose molecules can be described in terms of alternation of the configurational base unit that are enantiomeric (21a,c,d), are characterized by a regular enchainment of monomeric units having alternatively enantiomeric configurations, which produces couples of adjacent bonds having the same sign (3) (Fig. 6B). 6B with bond sequence . . (−)(+)(+)(−)(−)(+)(+)(−) .

The pairs (−, +) or (+, −) define a relative erythro configuration, whereas the pairs (+, +) or (−, −) define a relative threo configuration (3) (Fig. 10). 10. “Erythro” and “threo” relative configurations of two contiguous tetrahedral stereoisomeric centers, shown in rotated Fischer projections and zigzag chains, and configurational signs of the bond connecting the two carbon atoms. 11. Fischer projections and zigzag chains of erythro-diisotactic, threo-diisotactic and disyndiotactic polymers, with indication of the successions of (+) and (−) bonds.

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Crystals and crystallinity in polymers : diffraction analysis of ordered and disordered crystals by Claudio De Rosa


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